Background current elimination in thin layer ion-selective membrane coulometry

Stripping analysis of nanomolar perchlorate in drinking water with a voltammetric ion-selective electrode based on thin-layer liquid membrane.

A highly sensitive analytical method is required for the assessment of nanomolar perchlorate contamination in drinking water as an emerging environmental problem. We developed the novel approach based on a voltammetric ion-selective electrode to enable the electrochemical detection of "redox-inactive" perchlorate at a nanomolar level without its electrolysis. The perchlorate-selective electrode...

Selective Membrane Electrode for Bromide Ion Based on Aza Pyrilium Ion Derivative as a new Ionophore.

A highly selective electrode for Bromide ion based on aza pyrilium derivative as an excellentionophore is described.The sensor exhibits a good linear response with a slope of ( 60±1 ) mV per decadeover the concentration range of ( 1×10-3 – 9×10-6 M ) , and a detection limit of ( 3×10-6 M ) of Bromideions .The electrode response is independent of pH in the range of(4.0 –9.5).Selectivity coeffici...

Fe (II) Ion-Selective Membrane Electrode based onTetra-Phenyl Porphyrin in PVC Matrix

Fe2+ ion-selective membrane sensor has been fabricated from polyvinyl chloride (PVC) matrixmembrane containing neutral carrier tetra phenyl porphyrin (TPP) ionophore. The addition ofsodium tetraphenylborate (NaTPB) and the plasticizer DBP has been found to substantiallyimprove the performance of the sensor. The best performance was obtained with the sensor havinga membrane of composition of TPP...

selective membrane electrode for bromide ion based on aza pyrilium ion derivative as a new ionophore.

a highly selective electrode for bromide ion based on aza pyrilium derivative as an excellentionophore is described.the sensor exhibits a good linear response with a slope of ( 60±1 ) mv per decadeover the concentration range of ( 1×10-3 – 9×10-6 m ) , and a detection limit of ( 3×10-6 m ) of bromideions .the electrode response is independent of ph in the range of(4.0 –9.5).selectivity coeffici...

Selective Transport of Propylene by Silver Ion Complex Through an Immobilized Liquid Membrane